|
Fine grain
emulsions: VRP-M (green) and PFG-01 (red) |
|

Figure1: Spectral Sensitivity curves for VRP-M
(left) and PFG-01 (right).

Figure 2: Characteristic Curves for VRP-M
(left) and PFG-01 (right).

Figure 3: Grain Size Distribution Curve for VRP-M and PFG-01.

Figure 4: Diffraction Efficiency Curves for
VRP-M and PFG-01. |
|
Characteristic
curves of fine-grain red (PFG-01) and green (VRP-M) emulsions,
showing spectral sensitivity versus wavelength, are shown in Fig.1.
The VRP-M optical sensitivity (to CW radiation) is seen to peak at
approximately 75 microJ/cm2 and that of the PFG-01 (to CW radiation)
at approximately 80 microJ/cm2.
Fig.2
shows the optical density after exposure by CW radiation and after
development versus energy. Grain size characteristics for the
VRP-M and PFG-01 emulsions are shown in Fig.3.The
diffraction efficiency versus exposure for reflection holograms
recorded on PFG-01 (using a CW laser) and on VRP-M (using a pulsed
laser) is presented in Fig.4. The maximum
diffraction efficiency is seen to be >45% for both emulsions.
Material lifetime is more than two years.
The VRP-M and PFG-01 emulsions may be used equally well with
pulsed lasers and with CW radiation. In the pulsed laser radiation
case the emulsion should be post-sensitized with the technique of
latensification. The latensification technique is described below.
Table1 shows a summary of recommended
processing schemes for use with VRP-M when exposed by pulsed
Neodymium lasers (526.5nm, 532nm) and for use with VRP-M and
PFG-01 when exposed by CW Argon or by HeNe lasers. In the case of
exposure by CW radiation latensification is usually not necessary.
White-light holograms made on VRP-M have a natural green
reconstruction colour that can be easily changed by the technique
of colour -shifting using D-Sorbitol (described below).
White-light holograms made on PFG-01 have a natural yellow/orange
reconstruction colour when using a HeHe laser and the recommended
chemistry.
All chemicals necessary for the preparation of the recommended
solutions can be obtained from the following companies -
(i) Photographer’s Formulary Inc. (www.photoformulary.com),
(ii) Sigma-Aldrich www.sigma-aldrich.com),
For pulsed work one may also use the standard D-19 Kodak developer
if 6-8g of Methyl Phenidone is added into the final solution.
The temperature of all solutions described herein is 20 0C |
| VRP-M
&PFG-01 |
Mastering and Copying
with Pulsed Radiation |
Mastering and Copying
with CW Radiation. |
| Exposure: |
|
|
|
MASTERING
|
20-40 mJ/cm2 |
60-80 mJ/cm2 |
| COPYING |
30-60 mJ/cm2 |
70-90 mJ/cm2 |
| Latensification |
Yes |
If needed |
| Development |
SM-6,
2min |
CW-C2,
2min |
| Wash |
Water, 1-2min |
Water, 1-2min |
| Bleach |
PBU-Amidol
until clear (~2-3 min) |
PBU-Amidol
until clear (~2-3 min) |
| Wash |
Water 5 mins |
Water 5 mins |
| Final Wash |
Water with wetting
agent (Agepon) 1min |
Water with wetting
agent (Agepon) 1min |
| Drying |
Slow Air |
Slow Air |
Table 2: Recommended
Processing for VRP-M and PFG-01. |
|
SM-6
Developer
|
| Sodium Hydroxide |
12.0g |
| Methyl Phenidone |
6.0g |
| Ascorbic Acid |
18g |
| Sodium Phosphate (dibasic) |
28.4g |
| if 12H2O |
71.6g |
| Water |
to 1.0L |
|
CW-C2
Developer
1 part A + 1 part B
|
| Part A |
| Catechol |
20.0g |
| Ascorbic Acid |
10.0g |
| Sodium Sulphite (anhydrous) |
10.0g |
| Urea |
100.0g |
| Water |
to 1.0L |
| Part B |
| Sodium
Carbonate |
60.0g |
| Water |
to 1.0L |
| PBU-Amidol
Bleach |
| Potassium Persulphate |
10.0g |
| Citric Acid |
50.0g |
| Cupric Bromide |
1.0g |
| Potassium Bromide |
20.0g |
| Amidol |
1.0g |
| Water |
to 1.0L |
| Potassium
Iodide Bath |
| Potassium Iodide |
18.0g |
| Water |
to 1.0L |
Table 2: Developers, bleach and colour chance
bath

Figure 5: Hologram Colour versus
D-Sorbitol Solution Concentration for
exposure @ 526 nm
|
|
Latensification
PFG-01 and
VRP-M emulsions have peak sensitivities to exposures in the
millisecond regime. In order to obtain optimal sensitivity
to exposures different from this regime the technique of
latensification must be used.
Latensification is usually done directly after the
holographic exposure. Before applying the process a
latensification time appropriate for your system must be
worked out. This procedure is as follows: Place a 25W white
lamp at a distance of 1m from a test holoplate or film such
that its light uniformly illuminates the emulsion. You will
need to try several exposure times.
First of all you will need to develop the unexposed emulsion
under normal safelight conditions. The plate will darken a
little. This is called the “fog” level. After
development wash this control plate, dry and keep it handy.
Now a series of exposures with small test plates must be
made. Start at about 2 secs and go up to around 10 secs.
After each exposure develop your plate and match the
darkening of this plate to your control plate. If it is the
same, more exposure is needed so go back and repeat the
process. Stop when a result that is just marginally darker
than the fog level is obtained. This is then the correct
latensification exposure for your geometry.
Now that the proper latensification time has been
discovered, after every proper holoplate exposure you must
take your plate and illuminate it exactly as described above
for the time that you have worked out. Then all processing
is as normal.
Latensification stabilizes and enhances the latent image
formed by the holographic exposure. If required, chemical
processing may be done with significant delay after
latensification (~8 hours).
Colour
control
For the VRP-M
emulsion we recomend two colour shifting techniques. One
produces a fixed colour-shift towards the red of
approximately 50 nm. The other produces an adjustable colour
shift.
The fixed colour shifting is accomplished by soaking the
final hologram for 1 minute in a bath of Potassium
Iodide solution. Adjustable colour shifting is
accomplished by soaking the hologram for 1 minute in an
aqueous solution of D-Sorbitol (sugar substitute - C6H14O6)
with added wetting agent. The colour of the final hologram
depends on the solution concentration (Fig.5).
After soaking, the film must be taken out and put onto a
flat surface. Water drops must be removed using a
rubber wiper such as a windscreen wiper. Here one must be
delicate - if too much force is employed you may obtain a
somewhat different colour than that predicted by Fig.
5. If, after drying of the hologram, the replay colour
achieved is not satisfactory, the film or plate may be
washed in warm water and then soaked anew in another
D-Sorbitol solution of different concentration. |
| |
|
|
|
TITLE |
CHEMICAL |
FORMULA |
Sigma
Aldrich code |
Fluka
code |
|
SM-6 |
Sodium Hydroxide |
NaOH |
S 0899 |
71690 |
| |
Phenidone |
C6H5-C3H5N2O |
P 3441 |
79070 |
| |
Ascorbic Acid |
CH2OHCHOH(CHCOH:COHCOO) |
A 7506 |
95212 |
| |
Sodium Phosphate
(dibasic) |
Na2HPO4 |
S 0876 |
71642 |
|
CW-C2 |
Catechol |
C6H4-1,2-(OH)2 |
C 9510 |
15890 |
| |
Ascorbic Acid |
CH2OHCHOH(CHCOH:COHCOO) |
A 7506 |
95212 |
| |
Sodium Sulphite (anhy.) |
Na2SO3 |
S 8018 |
71990 |
| |
Urea |
NH2CONH2 |
U 1250 |
51460 |
| |
Sodium Carbonate |
Na2CO3 |
S 7795 |
71351 |
|
PBU-Amidol |
Potassium
Persulphate |
K2S2O8 |
P 9392 |
60490 |
| |
Citric Acid |
HOC(COOH)(CH2COOH)2 |
C 0759 |
27488 |
| |
Cupric Bromide |
CuBr2 |
- |
61185 |
| |
Potassium Bromide |
KBr |
P 9881 |
60095 |
| |
Amidol |
(NH2)2C6H3OH•2HCl |
23,010-3 |
33230 |
|
Bath |
Potassium Iodide |
KI |
P 8256 |
60400 |
|
Hardener |
Formalin 37% |
HCHO |
F 1635 |
47608 |
|
Table 3: Chemical
Formulas and suppliers codes. |
|
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are copyrighted by Geola uab and Slavich OAO.
Reproduction is illegal with prior agreement. 
|